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Lefty Gomez has the most career wins in All-Star Games, with 3 wins.

Most all star game wins as a player mlb
GomezSutterBlueMarichalDrysdaleFriendMillerDovalValdezOhtaniTanakaDíazKluberScherzerCainSaleClippardKimbrelCappsPriceBeckettPapelbon3222221111111111111111
NAMEWLW%GGSERASOCGSHOSVIPHERRHRBBHBPGFIBBTBFWPK/9BB/9K/BBHR/9K%BB%WHIPBABIPRAH/9
Lefty GomezLefty Gomez31.750552.50900018.01156230006804.501.503.001.0013.24.40.78.1673.005.50
Bruce SutterBruce Sutter201.000400.0070026.2200030312409.454.052.330.0029.212.50.75.1430.002.70
Vida BlueVida Blue201.000438.0070009.01288411004017.001.007.004.0017.52.51.44.2968.0012.00
Juan MarichalJuan Marichal201.000820.501200018.0712020206226.001.006.000.0019.43.20.50.1461.003.50
Don DrysdaleDon Drysdale21.667851.401900119.11034241106918.841.864.750.9327.55.80.72.1861.864.66
Bob FriendBob Friend21.667321.0850008.1812030013715.403.241.670.0013.58.11.32.2762.168.64
Mason MillerMason Miller101.000100.0020001.0000000003018.000.000.0066.70.00.00.0000.000.00
Camilo DovalCamilo Doval101.000100.0010001.010000000409.000.000.0025.00.01.00.3330.009.00
Framber ValdezFramber Valdez101.000100.0000001.000000000300.000.000.000.00.00.00.0000.000.00
Shohei OhtaniShohei Ohtani101.000110.0000001.000000000300.000.000.000.00.00.00.0000.000.00
Masahiro TanakaMasahiro Tanaka101.000100.0010001.010000000409.000.000.0025.00.01.00.3330.009.00
Edwin DíazEdwin Díaz101.0001018.0020001.0122110005018.009.002.009.0040.020.02.00.00018.009.00
Corey KluberCorey Kluber101.000100.0010001.000000000309.000.000.0033.30.00.00.0000.000.00
Max ScherzerMax Scherzer101.000641.29110007.04111100026014.141.2911.001.2942.33.80.71.2311.295.14
Matt CainMatt Cain101.000110.0010002.010000000704.500.000.0014.30.00.50.1670.004.50
Chris SaleChris Sale101.000632.2580008.0822101003209.000.001.1325.00.01.00.3182.259.00
Tyler ClippardTyler Clippard101.000200.0000001.010000000300.000.000.000.00.01.00.3330.009.00
Craig KimbrelCraig Kimbrel101.000701.59100015.24110501026115.887.942.000.0038.519.21.59.3641.596.35
Matt CappsMatt Capps101.000100.0010000.1000000001027.000.000.00100.00.00.000.000.00
David PriceDavid Price101.000310.0030004.0100000001206.750.000.0025.00.00.25.1110.002.25
Josh BeckettJosh Beckett101.000100.0020002.010000000709.000.000.0028.60.00.50.2000.004.50
Jonathan PapelbonJonathan Papelbon101.000400.0050003.12010001012013.500.000.0041.70.00.60.2862.705.40
Scott KazmirScott Kazmir101.000300.0020002.2100010101006.753.382.000.0020.010.00.75.1430.003.38
B.J. RyanB.J. Ryan101.000205.4010001.211100000605.400.000.0016.70.00.60.2005.405.40
Brendan DonnellyBrendan Donnelly101.000100.0010001.000000000309.000.000.0033.30.00.00.0000.000.00
Mark MulderMark Mulder
Mark BuehrleMark Buehrle
Freddy GarciaFreddy Garcia
James BaldwinJames Baldwin
Bartolo ColonBartolo Colon
Jose RosadoJose Rosado
Pedro MartinezPedro Martinez
Heathcliff SlocumbHeathcliff Slocumb
Kevin BrownKevin Brown
Jack McDowellJack McDowell
John SmoltzJohn Smoltz
Doug JonesDoug Jones
Frank ViolaFrank Viola
Bret SaberhagenBret Saberhagen
Roger ClemensRoger Clemens
LaMarr HoytLaMarr Hoyt
Jimmy KeyJimmy Key
Charlie LeaCharlie Lea
Lee SmithLee Smith
Dave StiebDave Stieb
Steve RogersSteve Rogers
Randy JonesRandy Jones
Jerry ReussJerry Reuss
Ken BrettKen Brett
Jon MatlackJon Matlack
Some of the information used here was obtained free of charge from Retrosheet.

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